Amperometric sensing of hydrogen peroxide using glassy carbon electrode modified with rhodium Rhodium-based amperometric sensor for H2O2 detection
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Abstract
Following our previous studies on the catalytic activity of electrochemically deposited on glassy carbon Rh electrocatalyst towards the reduction of hydrogen peroxide (H2O2), the electrochemical behaviour of the modified electrode was studied by means of cyclic voltammetry and chronoamperometry at pH-values from 5.0 to 9.0. The modified electrode exhibited a rapid, sensitive and reproducible response for the quantitative determination of H2O2 at low applied potential. Amperometry carried out at constant potential of 0 V (vs. Ag/AgCl, 3M KCl) at pH 6.0 (25 oC) gave the following operational parameters: detection limit of 4 μM, linear dynamic range 0.01 – 5.5 mM and electrode sensitivity of 377 μA mM−1 cm−2 .
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Beyer H., K. Kohler K. NOx removal by rhodium catalysts supported on carbon nanotubes: Evidence for the stoichiometric reduction of NO2 and NO by the carbon support. Applied Catalysis B: Environmental, 2010, 96(1-2): 110-116. https://doi.org/10.1016/j.apcatb.2010.02.008
Casella I., Contursi M. Highly dispersed rhodium particles on multi-walled carbon nanotubes for the electrochemical reduction of nitrate and nitrite ions in acid medium. ElectrochimicaActa,2014,138:447-453. https://doi.org/10.1016/j.electacta.2014.05.125
Dodevska T., Horozova E., Dimcheva N. Carbon electrodes modified with Rh: A comparative study of the catalytic activity in reduction of H2O2. Scientific Researches of the Union of Scientist of Bulgaria, Series C. Technics and Technologies, 2016, XIII: 20-23. [in Bulgarian]
Fang Y., Zhang D., Qin X., Miao Z., Takahashi S., Anzai J., Chen Q. A non-enzymatic hydrogen peroxide sensor based on poly(vinyl alcohol)-multiwalled carbon nanotubes-platinum nanoparticles hybrids modified glassy carbon electrode. Electrochimica Acta, 2012,70:266-271. https://doi.org/10.1016/j.electacta.2012.03.105
García S., Zhang L., Piburn G., Henkelman G., Humphrey S. Microwave synthesis of classically immiscible rhodium–silver and rhodium–gold alloy nanoparticles: Highly active hydrogenation catalysts. ACS Nano, 2014, 8(11): 11512-11521. https://doi.org/10.1021/nn504746u
Horozova Е.,Dimcheva N., Miteva M., Jordanova Z. Rhodium deposits on graphite: The impact of the graphite pad on the electrocatalytic activity in the electrooxidation of formic acid. Bulgarian Chemical Communications, 2008, 40(2): 129-136.
Jerkiewicz G., Borodzinski J. Relation between the surface states of oxide films at Rh electrodes and kinetics of the oxygen evolution reaction. Journal of the Chemical Society, FaradayTransactions, 1994,90:3669-3675. https://doi.org/10.1039/FT9949003669
Jia W., Guo M., Zheng Z., Yu T., Rodriguez E., Wang Y., Lei Y. Electrocatalytic oxidation and reduction of H2O2 on vertically aligned Co3O4 nanowalls electrode: Toward H2O2 detection. Journal of Electroanalytical Chemistry, 2009,625(1):27-32. https://doi.org/10.1016/j.jelechem.2008.09.020
Jiang F., Yue R., Du Y., Xu J., Yang P. A one-pot ‘green’ synthesis of Pd-decorated PEDOT nanospheres for nonenzymatic hydrogen peroxide sensing. Biosensors and Bioelectronics,2013,44:127-131. https://doi.org/10.1016/j.bios.2013.01.003
Kanaru V., Humphrey S., Kyffin J., Jefferson D., Burton J., Ambruster M., Lambert R. Evidence for heterogeneous Sonogashira coupling of phenylacetylene and iodobenzene catalyzed by well defined rhodium nanoparticles. Dalton Transactions, 2009, 7602-7605. https://doi.org/10.1039/B912833F
Ortiz R., Marquez O. P., Marquez J., Gutierrez C. Spectroelectrochemical evaluation of Rh microparticles as electrocatalyst for carbon monoxide and formic acid oxidation. Portugaliae Electrochimica Acta, 2006, 24(1): 105-116.
Pallotta C., de Tacconi N., Arvia A. Potentiodynamic behaviour of the rhodium/H2SO4 (aq) interface in the potential range of the hydrogen and oxygen electrosorption. ElectrochimicaActa,1981,26(2):261-273. https://doi.org/10.1016/0013-4686(81)85012-8
Park K., Jang K., Kim H., Son S. Near-monodisperse tetrahedral rhodium nanoparticles on charcoal: The shape-dependent catalytic hydrogenation of arenes. Angewandte Chemie International Edition, 2007, 46(7): 1152-1155. https://doi.org/10.1002/anie.200603961
Qin X., Wang H., Wang X., Miao Z., Fang Y., Chen Q., Shao X. Synthesis of dendritic silver nanostructures and their application in hydrogen peroxide electroreduction. Electrochimica Acta, 2011, 56(9): 3170-3174. https://doi.org/10.1016/j.electacta.2011.01.058
Qu F., Yang M., Shen G., Yu R. Electrochemical biosensing utilizing synergic action of carbon nanotubes and platinum nanowires prepared by template synthesis. Biosensors and Bioelectronics,2007,22(8):1749-1755. https://doi.org/10.1016/j.bios.2006.08.003
Sathe B., Balan B., Pillai V. Enhanced electrocatalytic performance of interconnected Rh nano-chains towards formic acid oxidation. Energy and Environmental Science, 2011,4(3):1029-1036 http://dx.doi.org/10.1039/C0EE00219D
Villiard F., Jerkiewicz G. Comprehensive studies of formation and reduction of surface oxides at rhodium electrodes at 298 K. Canadian Journal of Chemistry, 1997, 75(11): 1656-1665. https://doi.org/10.1139/v97-197
Yuan Q., Zhou Z., Zhuang Z., Wang X. Tunable aqueous phase synthesis and shape-dependent electrochemical properties of rhodium nanostructures. Inorganic Chemistry, 2010, 49(12): 5515-5521. https://doi.org/10.1021/ic100249t
Zhong L., Gan S., Fu X., Li F., Han D., Guo L., Niu L. Electrochemically controlled growth of silver nanocrystals on graphene thin film and applications for efficient nonenzymatic H2O2 biosensor. Electrochimica Acta, 2013, 89:222-228. https://doi.org/10.1016/j.electacta.2012.10.161
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