Removal of 2-naphtol orange by industrial rose and lavender solid by-products in dynamic conditions Removal of 2-naphtol orange by rose and lavender by-products
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Abstract
Rosa damascena Mill. (RD) and Lavandula angustifolia Mill. (L) biomasses – by-products of essential oil manufacturing were utilized as renewable and nature-friendly adsorbents for removal of 2-naphthol orange (2NO) in column adsorption model (dynamic conditions). The amount of proteins in the biomasses were 11.60±0.68% for RD and 8.65±0.20 for L, and the polyuronide content for both residues was around 7.50%. The dynamic adsorption of 2NO was investigated in five solutions with different pH, namely 0.1 N H2SO4 (1.21), deionized water (3.63), 50 mM citrate buffer (5.49), 50 mM phosphate buffer (8.30) and 0.05 N NaOH (12.80). Preliminary washing of RD and L residues with 0.1 N HCl increased their removal efficiency compared with water washed biomasses. At pH range from 1.21 to 5.49 the 2NO removal was above 89.0±0.1% for RD and 84.2±0.1% for L. The present work demonstrated that RD and L biomasses were able to remove 2NO in dynamic conditions (column adsorption) from water solutions with 89.0±0.1% and 84.2±0.1% efficiency, respectively.
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References
Crettaz S., Kämpfer P., Brüschweiler B., Nussbaumer S., Deflorin O. Survey on hazardous non-regulated aromatic amines as cleavage products of azo dyes found in clothing textiles on the Swiss market. JCF, 2020, 15(8): 49-61. https://doi.org/10.1007/s00003-019-01245-1
Echavarria-Alvarez A., Hormaza-Anaguano A. Flower wastes as a low-cost adsorbent for the removal of acid blue 9. Dyna, 2014, 81(185): 132-138. Available at: https://www.redalyc.org/pdf/496/49631031019.pdf
Hambarliyska I., Manousakis D., Marovska G., Bylianova A., Slavov A. Adsorption and removal of Acid orange 7 using industrial essential oil solid by-products of melissa (Melissa officinalis) and yarrow (Achillea millefolium). Food Science and Applied Biotechnology, 2025, 8(1): 147-155. https://doi.org/10.30721/fsab2025.v8.i1.479
Kaya A., Şahin S. Acid orange 7 adsorption onto quaternized pistachio shell powder from aqueous solutions. Biomass Conversion and Biorefinery, 2022, 12(2): 6015-6032. https://doi.org/10.1007/s13399-022-02414-3
Khalil A., Mangwandi C., Salem M., Ragab S., el Nemr A. Orange peel magnetic activated carbon for removal of acid orange 7 dye from water. Scientific Reports, 2024, 14(1): 119. https://doi.org/10.1038/s41598-023-50273-3
Khan N., Ahmad A., Sharma V., Saha A., Pandey A., Bhargava P. An integrative study for efficient removal of hazardous azo dye using microbe-immobilized cow dung biochar in a continuous packed bed reactor. Renewable Energy, 2022, 200(11): 1589-1601. https://doi.org/10.1016/j.renene.2022.10.016
Kovacheva N., Rusanov K., Atanassov I. Industrial cultivation of oil bearing rose and rose oil production in Bulgaria during 21st century, directions and challenges. Biotechnology & Biotechnolical Equipment, 2010, 24(2): 1793-1798. http://doi.org/10.2478/v10133-010-0032-4
Marovska G., Dushkova M., Angelova G., Brazkova M., Brink H., Haneklaus N., Menkov N., Slavov A. Rose and lavender industrial by-products application for adsorption of Acid orange 7 from aqueous solution. Biomass Conversion and Biorefinery, 2023, 14(8): 22703-22716. https://doi.org/10.1007/s13399-023-04702-y
Marovska G., Slavov A. Utilization of industrial rose and lavender solid by-products for removal of 2-naphtol orange. Scientific Papers. Series B, Horticulture, 2023, LXVII(2): 508-513.
Naraghi B., Zabihi F., Narooie M., Saeidi M., Biglari H. Removal of Acid Orange 7 dye from aqueous solutions by adsorption onto Kenya tea pulps; granulated shape. Electronic Physician, 2017, 9(5): 4312-4321. https://doi.org/10.19082/4312
Nistor M., Halip L., Muntean S., Kurunczi L., Costișor O. Modeling and optimization of Acid Orange 7 adsorption process using magnetite/carbon nanocomposite. Sustainable Chemistry and Pharmacy, 2022, 29(10): 100778. https://doi.org/10.1016/j.scp.2022.100778
Ouakouak A., Abdelhamid M., Thouraya B., Chahinez H., Hocine G., Hamdi N., Syafiuddin A., Boopathy R. Development of a novel adsorbent prepared from dredging sediment for effective removal of dye in aqueous solutions. Applied Science, 2021, 11(22): 10722. https://doi.org/10.3390/app112210722
Rabbani D., Mahmoudkashi N., Mehdizad F., Shaterian M. Green approach to wastewater treatment by application of Rosa damascena waste as nano-biosorbent. Journal of Environmental Science and Technology, 2016, 9(1): 121-130. https://doi.org/10.3923/jest.2016.121.130
Rathi B., Kumar P. Sustainable approach on the biodegradation of azo dyes: A short review. Current Opinion in Green and Sustainable Chemistry, 2022, 33(2): 100578. https://doi.org/10.1016/j.cogsc.2021.100578
Slavov A., Vasileva I., Stefanov L., Stoyanova A. Valorization of wastes from the rose oil industry, Reviews in Environmental Science and Bio/Technology, 2017, 16(2): 309-325. https://doi.org/10.1007/s11157-017-9430-5
Slavov A., Topuzova M., Marovska G. By-products from the essential oil industry – valorization and recycling. Practical application – adsorption of textile industry dyes. Scientific Papers. Series B, Horticulture, 2023, LXVII(1): 838-845.
Stoyanova A. Handbook of the specialists in aroma industry (First Edition). Bulgarian national association of essential oils, perfumery and cosmetics, Plovdiv, Bulgaria. 2022, 664 pages. Print ISBN: 978-619-92133-0-8
Wu Y., Hu Y., Xie Z., Feng S., Li B., Mi X. Characterization of biosorption process of acid orange 7 on waste brewery's yeast. Applied Biochemistry and Biotechnology, 2011, 163(7): 882-894. https://doi.org/10.1007/s12010-010-9092-z

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